suppressor column - in ion chromatography, refers to the column placed after the ion-exchange column. Its purpose is to remove or suppress the ionization of buffer ions so that sample ions can be observed in a weakly conducting background with a conductivity detector.
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surface area - in an adsorbent, refers to the total area of the solid surface as determined by an accepted measurement technique such as the BET method using nitrogen adsorption. The surface area of a typical porous adsorbent such as silica gel can vary from 100 to 600 m2/g.
See surface area.
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surface chemistry - chemical and physico-chemical properties of the adsorbent surface. Interactions of the analyte with the adsorbent surface depends on the type of the ligands chemically attached to the surface.
See surface chemistry.
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surface coverage - usually refers to the mass of bonded ligands per unit area of an adsorbent. Often expressed in mole/m2 of surface. Sometimes the %C is given as an indicator of surface coverage.
See bonding density.
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swelling - process in which resins and gels increase their volume because of their solvent environment. Solvent enters ion-exchange resin to dilute ions; in gels, solvent penetrates pores. If swelling occurs in packed columns, blockage or increased back pressure can occur. In addition, column efficiency can be affected.